上次我碰到了，但没细看。

Biochimica et Biophysica Acta (BBA) - Bioenergetics
Volume 1757, Issue 11, November 2006, Pages 1453-1459
doi:10.1016/j.bbabio.2006.05.017 | How to Cite or Link Using DOI
Copyright © 2006 Elsevier B.V. All rights reserved.      Cited By in Scopus (6)
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Review
Commentary on: “Photosynthesis and negative entropy production” by Jennings and coworkers

Jérôme Lavergnea
Abstract

This commentary argues against the view that photochemical energy conversion violates the second law of thermodynamics, as expressed in a recent paper [r.c. jennings, e. engelmann, f. garlaschi, a.p. casazza, g. zucchelli. photosynthesis and negative entropy production. biochim. biophys. acta 1709 (2005) 251-255]. The basic principles of free energy conversion by a photo-electrochemical cell are outlined, emphasizing the fact that the potential depends on the relative population of the excited state and thus on the illumination intensity.

Keywords: Photosynthesis; Thermodynamic; Energy yield; Second law; Dissipation; Carnot; Entropy; Photochemical energy conversion; Solar energy conversion